HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine hydrate (1:1) → (1R,8S)-5-Cyclopropyl-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | Camphoroquinone | HCID 641916 | — |
| Reactant | Dimethyl (2-cyclopropyl-2-oxoethyl)phosphonate | HCID 57624838 | — |
| Product | (1R,8S)-5-Cyclopropyl-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene | HCID 67365663 | — |
Reaction Steps
colorless oil. MS (EI): 228.3 (M+). Prepared from (1R,4S)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, (2-Cyclopropyl-2-oxo-ethyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07678795B2 |
| Source dataset | uspto-grants-2010_03 |
| ORD ID | ord-89907ad70fa744eab992a4da04d07998 |
| Source note | uspto-grants-2010_03 |