1-(3-Nitrophenyl)-1H-1,2,3-triazole → 3-(1H-1,2,3-triazol-1-yl)benzenamine

Participants

Reaction Steps

1-(3-Nitro-phenyl)-1H-[1,2,3]triazole (9.66 g, 51 mmol) were dissolved in 300 ml methanol and 70 ml THF. Palladium on charcoal (10%, 500 mg) were added and the reaction mixture was stirred with a hydrogen balloon for 36 h. Palladium on charcoal was filtered off and washed with methanol. The solvent was evaporated off to yield the title compound (8.3 g, 100%) as an off-white solid, mp 71-73° C.

Provenance & Evidence