Benzene → 2,3-Dimethyl-5-allyl-6-tetradecanoylhydroquinone

HRID 224469Notes

Reaction equation

HRID 224469 reaction equation
C([O:4][C:5]1[C:10]([C:11](=[O:25])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])=[CH:9][C:8]([OH:26])=[C:7]([CH3:27])[C:6]=1[CH3:28])C=C.[CH:29]1[CH:34]=CC=C[CH:30]=1>>[CH3:28][C:6]1[C:7]([CH3:27])=[C:8]([OH:26])[C:9]([CH2:34][CH:29]=[CH2:30])=[C:10]([C:11](=[O:25])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[C:5]=1[OH:4]

Participants

3

Reactant 2

HCID 241BenzeneHCID 233332484-Hydroxy-2,3-dimethyl-6-tetradecanoylphenyl allyl ether

Product 1

HCID 205104582,3-Dimethyl-5-allyl-6-tetradecanoylhydroquinone

Procedure

90 g of the allyl ether of step 2 were heated to 210° C. under nitrogen atmosphere within 2 h. After cooling the melt was dissolved in 300 ml of benzine (boiling range: 50°-75° C.) and placed in a cool place. The precipitate formed was filtered with suction the next day.

Workup

  1. temperatureAfter cooling the melt
  2. customThe precipitate formed
  3. filtrationwas filtered with suction the next day

Sources & evidence

ORD record
ord-7c05fbbb7b284f8d945e48ff232f998e
Source dataset
uspto-grants-1980_11
Patent number
US04232107

Reaction notes

Loading…