HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2245229Generated: October 30, 2026
Potassium Carbonate → HCID 135526516, compound
https://huagongshe.com/reaction/2245229
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol | HCID 2734622 | — |
| Reactant | HCID 58853195 | HCID 58853195 | — |
| Catalyst | HCID 178418397 | HCID 178418397 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Solvent | Acetonitrile--water (1/1) | HCID 18373917 | — |
| Product | HCID 135526516 | HCID 135526516 | — |
Reaction Steps
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-phenol (25 μL, 120/μmol), 1a (36 mg, 100 μmol), Pd(Ph3P)4 (12 mg, 10 μmol), K2CO3 (28 mg, 200 μmol), CH3CN (900 μL), and H2O(100 μL) were sealed in a microwave vessel and heated by microwave irradiation at 120° C. for 15 minutes. The reaction was filtered and purified by reverse phase HPLC to give 4. (10%-99% CH3CN/H2O), (10%-99% CH3CN (0.035% TFA)/H2O(0.05% TFA). LCMS: m/z 370.1 (M+H)+ at 2.89 minutes (10%-99% CH3CN/H2O), (10%-99% CH3CN (0.035% TFA)/H2O(0.05% TFA).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07683065B2 |
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| Source dataset | uspto-grants-2010_03 |
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| ORD ID | ord-f96606565ae0488fb9f0a44f041e1c0a |
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| Source note | uspto-grants-2010_03 |
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