Benzenamine, 3,5-bis(trifluoromethyl)- → HCID 59816222, compound

HRID 2245628Notes

Reaction equation

HRID 2245628 reaction equation
[F:1][C:2]([F:15])([F:14])[C:3]1[CH:4]=[C:5]([CH:7]=[C:8]([C:10]([F:13])([F:12])[F:11])[CH:9]=1)[NH2:6].[CH2:16]1[C:29]2[C:20](=[N:21][C:22]3[C:23](=O)[CH2:24][CH2:25][CH2:26][C:27]=3[CH:28]=2)[C:19](=O)[CH2:18][CH2:17]1>>[F:1][C:2]([F:14])([F:15])[C:3]1[CH:4]=[C:5]([N:6]=[C:19]2[C:20]3[C:29](=[CH:28][C:27]4[CH2:26][CH2:25][CH2:24][C:23](=[N:6][C:5]5[CH:7]=[C:8]([C:10]([F:11])([F:12])[F:13])[CH:9]=[C:3]([C:2]([F:1])([F:14])[F:15])[CH:4]=5)[C:22]=4[N:21]=3)[CH2:16][CH2:17][CH2:18]2)[CH:7]=[C:8]([C:10]([F:11])([F:12])[F:13])[CH:9]=1

Participants

3

Reactant 2

HCID 9480Benzenamine, 3,5-bis(trifluoromethyl)-HCID 355603HCID 355603, compound

Product 1

HCID 59816222HCID 59816222, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4: 3,5-bis-trifluoromethylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis[3,5-bistrifluoromethylphenylimino]-1,2,3,4,5,6,7,8-octahydroacridine (5). The complexation of (5) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of the final complex was proved by direct probe GC. Exact mass direct probe calculated for C29H19Cl2F12FeN3: 763.01. Found: 763.01.

Workup

  1. customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record
ord-a842bd535fb74e58867a9710eaf98e7d
Source dataset
uspto-grants-2010_03
Patent number
US07683149B2

Reaction notes

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