HCID 355603, compound → HCID 59816219, compound

HRID 2245629Notes

Reaction equation

HRID 2245629 reaction equation
[C:1]1([C:7]2[CH:13]=[CH:12][CH:11]=[C:10]([C:14]3[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=3)[C:8]=2[NH2:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:20]1[C:33]2[C:24](=[N:25][C:26]3[C:27](=O)[CH2:28][CH2:29][CH2:30][C:31]=3[CH:32]=2)[C:23](=O)[CH2:22][CH2:21]1>>[C:14]1([C:10]2[CH:11]=[CH:12][CH:13]=[C:7]([C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)[C:8]=2[N:9]=[C:23]2[C:24]3[C:33](=[CH:32][C:31]4[CH2:30][CH2:29][CH2:28][C:27](=[N:9][C:8]5[C:10]([C:14]6[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=6)=[CH:11][CH:12]=[CH:13][C:7]=5[C:1]5[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=5)[C:26]=4[N:25]=3)[CH2:20][CH2:21][CH2:22]2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

3

Reactant 2

HCID 355603HCID 355603, compoundHCID 110102262,6-diphenylaniline

Product 1

HCID 59816219HCID 59816219, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4: 2,6-diphenylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis[2,6-diphenylphenylimino]-1,2,3,4,5,6,7,8-octahydroacridine (6). Complexation of (6) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of final complex was proved by direct probe GC. Exact mass direct probe calculated for C49H39Cl2FeN3: 795.19. Found: 795.19.

Workup

  1. customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record
ord-6e923044137c4e65833efbf7d21c0514
Source dataset
uspto-grants-2010_03
Patent number
US07683149B2

Reaction notes

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