2-Aminobiphenyl → HCID 59816213, compound

HRID 2245630Notes

Reaction equation

[C:1]1([C:7]2[CH:13]=[CH:12][CH:11]=[CH:10][C:8]=2[NH2:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:14]1[C:27]2[C:18](=[N:19][C:20]3[C:21](=O)[CH2:22][CH2:23][CH2:24][C:25]=3[CH:26]=2)[C:17](=O)[CH2:16][CH2:15]1>>[C:1]1([C:7]2[CH:13]=[CH:12][CH:11]=[CH:10][C:8]=2[N:9]=[C:17]2[C:18]3[C:27](=[CH:26][C:25]4[CH2:24][CH2:23][CH2:22][C:21](=[N:9][C:8]5[CH:10]=[CH:11][CH:12]=[CH:13][C:7]=5[C:1]5[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=5)[C:20]=4[N:19]=3)[CH2:14][CH2:15][CH2:16]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

Reactant 2

HCID 70152-Aminobiphenyl

HCID 355603HCID 355603, compound

Product 1

HCID 59816213HCID 59816213, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4: 2-phenylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis(2-phenylphenylimino)-1,2,3,4,5,6,7,8-octahydroacridine (7). The complexation of (7) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of the final complex was proved by direct probe GC. Exact mass direct probe calculated for C37H31Cl2FeN3: 643.12. Found: 643.12.

Workup

customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record: ord-ae2877c546b743999b50d385f9d94257
Source dataset: uspto-grants-2010_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07683149B2

Reaction notes

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