Ammonia → HCID 5484329, compound

HRID 224567Notes

Reaction equation

HRID 224567 reaction equation
[NH3:1].[C:2]1(C(O)C)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.O=O.[C:13]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=O)[CH3:14].C([N:33]([CH2:38][C:39](O)=O)CC(O)=O)CN(CC(O)=O)CC(O)=O>>[CH3:14]/[C:13](/[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)=[N:1]\[N:33]=[C:38](/[CH3:39])\[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

6

Reactant 5

HCID 222AmmoniaHCID 977OxygenHCID 6049Ethylenediaminetetraacetic AcidHCID 74091-PhenylethanolHCID 7410Acetophenone

Product 1

HCID 5484329HCID 5484329, compound

Procedure

The reaction was carried out by moderately introducing gaseous ammonia, with stirring, into a mixture of 17.0 g of the reaction mixture (which was prepared by oxidizing 1-phenyl ethanol with oxygen and which contained 1.263 m mol/g of peroxide compounds), 2 g of acetophenone, 0.02 g of EDTA.2Na and 2 g of the silica gel used in Example 2, for 6 hours, at a temperature of 120° C. The yield of the acetophenone-azine thus produced was 3.9%.

Workup

  1. customwas prepared

Sources & evidence

ORD record
ord-140b66aae6394d738177d705fe1d9eb8
Source dataset
uspto-grants-1980_11
Patent number
US04233242

Reaction notes

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