Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hexanal | HCID 6184 | — |
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Catalyst | Copper | HCID 23978 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-Nonen-4-ol | HCID 141975 | — |
Reaction Steps
3500 ml water, 200 g hexanal (2 mol) and 305 g allyl chloride (4 mol), 900 g tin(II) chloride dihydrate (2 mol) and 25 g copper powder (0.4 mol) was added into a 61 flask. The reaction mixture was stirred at ca. 30° C. for 8 h. The organic phase was separated by decantation or centrifugation and the crude raw product distilled in vacuo to give 4-hydroxy-1-nonene. MS: m/z 141 (M-1), 101 (M-C3H5), 124 (M-18), 83 (101-18), 55 (83-C2H4).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07683187B2 |
|---|
| Source dataset | uspto-grants-2010_03 |
|---|
| ORD ID | ord-531e5312285443be89e9db694cac0df4 |
|---|
| Source note | uspto-grants-2010_03 |
|---|
