Potassium → HCID 23332056, compound

HRID 224691Notes

Reaction equation

HRID 224691 reaction equation
[K].[Cl:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[S:13][C:12]([C:14](=[O:18])[C:15]([OH:17])=[O:16])=[CH:11][CH:10]=2)=[CH:5][CH:4]=1>>[Cl:2][C:3]1[CH:4]=[CH:5][C:6]([C:9]2[S:13][C:12]([CH:14]([OH:18])[C:15]([OH:17])=[O:16])=[CH:11][CH:10]=2)=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 5462222PotassiumHCID 23332057HCID 23332057, compound

Product 1

HCID 23332056HCID 23332056, compound

Procedure

When the above procedure was repeated starting with the potassium salt of 5-(4-chlorophenyl)thien-2-ylglyoxylic acid, there was obtained 5-(4-chlorophenyl)thien-2-ylglycolic acid, m.p. 158°-160° C.

Sources & evidence

ORD record
ord-13ea1371459c4bd89819cf2412b2ab77
Source dataset
uspto-grants-1980_11
Patent number
US04233452

Reaction notes

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