Nitric Acid → Galactose 6-phosphate

HRID 224743Notes

Reaction equation

HRID 224743 reaction equation
[OH-].[Na+].[P:3]([O:7][CH2:8][C@@H:9]([OH:18])[C@H:10]([OH:17])[C@H:11]([OH:16])[C@@H:12]([OH:15])[CH:13]=[O:14])([O-:6])([O-:5])=[O:4].[Ba+2].[N+]([O-])(O)=O>O>[P:3]([O:7][CH2:8][C@@H:9]([OH:18])[C@H:10]([OH:17])[C@H:11]([OH:16])[C@@H:12]([OH:15])[CH:13]=[O:14])([OH:5])([OH:6])=[O:4]

Participants

5

Reactant 3

HCID 944Nitric AcidHCID 14798Sodium HydroxideHCID 107521Barium 6-O-phosphonatohexose

Product 1

HCID 3034794Galactose 6-phosphate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The pH of an 11.3-ml aqueous solution of 0.67M cis-[Pt(NH3)2 (H2O)2 ](NO3)2 was adjusted with sodium hydroxide to 4. Then, 3.0 grams of barium D-galactose-6-phosphate dissolved in 30 ml water were added. The pH of the resulting solution was adjusted to 5.0 with 2 M nitric acid. After stoppering the solution with a porous plug and stirring for 21 days, the above-identified complex which had formed during that time period was recovered as a water-insoluble blue precipitate by the method described in Example 5.

Workup

  1. additionwere added
  2. customthe above-identified complex which had formed during that time period
  3. customwas recovered as a water-insoluble blue precipitate by the method

Sources & evidence

ORD record
ord-23351a7d2f3742838512e7ff92897a09
Source dataset
uspto-grants-1980_11
Patent number
US04234499

Reaction notes

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