HCID 71306746, compound → Fosfructose

HRID 224745Notes

Reaction equation

HRID 224745 reaction equation
[P:1]([O:5][CH2:6][C:7]([C@H:9]([C@@H:11]([C@@H:13]([CH2:15][O:16][P:17]([OH:20])([O-:19])=[O:18])[OH:14])[OH:12])[OH:10])=[O:8])([O-:4])([O-:3])=[O:2].[Na+].[Na+].[Na+]>O>[P:1]([O:5][CH2:6][C:7]([C@H:9]([C@@H:11]([C@@H:13]([CH2:15][O:16][P:17]([OH:19])([OH:20])=[O:18])[OH:14])[OH:12])[OH:10])=[O:8])([OH:4])([OH:3])=[O:2]

Participants

3

Reactant 1

HCID 71306746HCID 71306746, compound

Product 1

HCID 84951Fosfructose

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

A 5.0 gram portion of trisodium D-fructose-1,6-diphosphate was dissolved in 10 ml water. The resulting solution was added to 14.1 ml of a 0.67 M aqueous solution of cis-[Pt(NH3)2 (H2O)2 ](NO3)2. The reaction mixture was allowed to stand for 28 days in a 40° C. bath. After that time, the dark blue water-insoluble precipitate which had formed was filtered, washed with water and ethanol, and then dried in vacuum, to yield 0.566 grams of the above-identified complex.

Workup

  1. filtrationwas filtered
  2. washwashed with water and ethanol
  3. customdried in vacuum

Sources & evidence

ORD record
ord-2fd69d71b32f4beb8b79d5060f8d37dc
Source dataset
uspto-grants-1980_11
Patent number
US04234499

Reaction notes

Loading…