Ethyl chlorothioformate → HCID 15662576, compound

HRID 2248179Notes

Reaction equation

HRID 2248179 reaction equation
ClC(S[CH2:5][CH3:6])=O.[CH3:7]C(SC1C=CC(SCCO)=CC=1)CC.[CH3:22][CH:23]([O:26][C:27]1[CH:36]=[CH:35][C:30]([O:31][CH2:32][CH2:33][OH:34])=[CH:29][CH:28]=1)CC.CC(C)=CCSC1C=CC(SCCO)=CC=1.CC(SC1C=CC(OCCO)=CC=1)CC>>[CH3:7][C:5]([CH3:6])=[CH:22][CH2:23][O:26][C:27]1[CH:36]=[CH:35][C:30]([O:31][CH2:32][CH2:33][OH:34])=[CH:29][CH:28]=1

Participants

6

Reactant 5

HCID 18056Ethyl chlorothioformateHCID 13939035HCID 13939035, compoundHCID 14852817HCID 14852817, compoundHCID 15662558HCID 15662558, compoundHCID 19816531HCID 19816531, compound

Product 1

HCID 15662576HCID 15662576, compound

Procedure

In the same manner, S-ethyl chlorothioformate is reacted with each of 2-[4(1-methylpropylthio)phenylthio]ethanol, 2-[4(1-methylpropoxy)phenoxy]ethanol, 2-[4(3-methyl-2-butenylthio)phenylthio]ethanol and 2-[4(1-methylpropylthio)phenoxy]ethanol to give, respectively, compounds 64, 65, 66, 67 and 84 under Table A.

Workup

  1. customto give

Sources & evidence

ORD record
ord-944c731058e04b04abe0b199c397601c
Source dataset
uspto-grants-1991_08
Patent number
US05037991

Reaction notes

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