Ethanolamine → HCID 19996293, compound

HRID 2248423Notes

Reaction equation

HRID 2248423 reaction equation
[OH:1][C:2]1[C:11]([CH3:12])=[CH:10][C:5]([C:6]([O:8]C)=O)=[CH:4][C:3]=1[CH3:13].[CH2:14]([CH2:16][NH2:17])[OH:15]>>[OH:15][CH2:14][CH2:16][NH:17][C:6](=[O:8])[C:5]1[CH:4]=[C:3]([CH3:13])[C:2]([OH:1])=[C:11]([CH3:12])[CH:10]=1

Participants

3

Reactant 2

HCID 700EthanolamineHCID 12389264Methyl 4-hydroxy-3,5-dimethylbenzoate

Product 1

HCID 19996293HCID 19996293, compound

Procedure

A 270 g quantity of methyl 4-hydroxy-3,5-dimethylbenzoate is heated in 300 ml of ethanolamine for 6 hours at a bath temperature of 160° C. while simultaneously removing the methanol which forms by distillation. The excess ethanolamine is removed under vacuum. The glassy product is ground, screened (1 mm screen), and dried thoroughly at 0.5 torr and 60° C. for a yield of 307 g.

Workup

  1. customwhile simultaneously removing the methanol which
  2. distillationforms by distillation
  3. customThe excess ethanolamine is removed under vacuum
  4. customdried thoroughly at 0.5 torr and 60° C. for a yield of 307 g

Sources & evidence

ORD record
ord-a66c128bbd404c6bb6572076435813fe
Source dataset
uspto-grants-1991_08
Patent number
US05039781

Reaction notes

Loading…