HCID 19995066, compound → Dimethylamine

HRID 2248839Notes

Reaction equation

HRID 2248839 reaction equation
[CH3:1][NH:2][Al:3]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH3:16][N:17]=[Al][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>>[C:4]1([Al:3]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH3:16][NH:2][CH3:1].[C:4]1([Al:3]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH3:1][NH:17][CH3:16]

Participants

5

Reactant 2

HCID 19995066HCID 19995066, compoundHCID 19995067HCID 19995067, compound

Product 3

HCID 674DimethylamineHCID 16684219Aluminum, triphenyl-HCID 19810334HCID 19810334, compound

Procedure

Laubengayer et al., Inorg. Chem., 1, pages 632 to 637 (1962), disclose the reaction of triphenylaluminum and methylamine in toluene solution to form methylamine triphenylaluminum, then methylaminodiphenylaluminum, and then methyliminophenylaluminum. Triphenylaluminum and dimethylamine form dimethylamine triphenylaluminum which is heated to form dimethylaminodiphenylaluminum.

Sources & evidence

ORD record
ord-940a6c9d3ae64c27ae1603441649009f
Source dataset
uspto-grants-1991_08
Patent number
US05041512

Reaction notes

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