Formaldehyde → HCID 23330770, compound

HRID 224919Notes

Reaction equation

HRID 224919 reaction equation
[CH3:1][C:2]1([CH3:39])[CH2:7][CH:6]([NH:8][C:9]2[N:14]=[C:13]([NH:15][CH:16]3[CH2:21][C:20]([CH3:23])([CH3:22])[NH:19][C:18]([CH3:25])([CH3:24])[CH2:17]3)[N:12]=[C:11]([NH:26][CH:27]3[CH2:32][C:31]([CH3:34])([CH3:33])[NH:30][C:29]([CH3:36])([CH3:35])[CH2:28]3)[N:10]=2)[CH2:5][C:4]([CH3:38])([CH3:37])[NH:3]1.[CH2:40]=[O:41].[OH-].[Na+]>C(O)(=O)C.O>[CH3:33][C:31]1([CH3:34])[CH2:32][CH:27]([NH:26][C:11]2[N:10]=[C:9]([NH:8][CH:6]3[CH2:5][C:4]([CH3:38])([CH3:37])[NH:3][C:2]([CH3:39])([CH3:1])[CH2:7]3)[N:14]=[C:13]([N:15]([CH:16]3[CH2:17][C:18]([CH3:24])([CH3:25])[NH:19][C:20]([CH3:22])([CH3:23])[CH2:21]3)[CH2:40][OH:41])[N:12]=2)[CH2:28][C:29]([CH3:36])([CH3:35])[NH:30]1

Participants

6

Reactant 3

HCID 712FormaldehydeHCID 14798Sodium HydroxideHCID 15883572HCID 15883572, compound

Product 1

HCID 23330770HCID 23330770, compound

Reagents, catalysts & solvents 2

HCID 176Acetic AcidSolventHCID 962WaterSolvent

Procedure

54.3 g of 2,4,6-tris-(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazine are dissolved in 200 ml of glacial acetic acid. After addition of 20 ml of 36% formaldehyde solution, the reaction mixture is stirred for 18 hours at room temperature, then diluted with water, made strongly alkaline with concentrated sodium hydroxide solution and extracted with toluene. The toluene solution is dried over sodium sulphate and concentrated in vacuo. Crystallisation of the residue yields 2,4-bis-(2,2,6,6-tetramethyl-4-piperidylamino)-6-(2,2,6,6-tetramethyl-4-piperidyl-methylolamino)-1,3,5-triazine in the form of colourless crystals with a melting point of 201°-202° C.

Workup

  1. extractionextracted with toluene
  2. dry with materialThe toluene solution is dried over sodium sulphate
  3. concentrationconcentrated in vacuo
  4. customCrystallisation of the residue

Sources & evidence

ORD record
ord-17f8a185af524b2486101657f860512b
Source dataset
uspto-grants-1980_11
Patent number
US04234728

Reaction notes

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