HCID 12490074, compound → HCID 178454898, compound

HRID 224992Notes

Reaction equation

HRID 224992 reaction equation
C(P([C:6]1[CH:11]=CC=C[CH:7]=1)OC)C.[CH2:12]([P:14](C1C=CC=CC=1)([C:16]1[N:21]=[C:20]([P:22]([CH2:30]C)(C2C=CC=CC=2)=[O:23])[CH:19]=[C:18]([P:32](CC)([C:34]2[CH:39]=[CH:38]C=CC=2)=[O:33])[N:17]=1)=[O:15])C.[CH2:48](P(CCC)OCC)[CH2:49][CH3:50].[CH2:58](P(CCC)(C1N=C(P(CCC)(CCC)=O)C=C(P(CCC)(CCC)=O)N=1)=O)CC.C(P(CC(C)C)OC)C(C)C>>[CH2:12]([PH:14]([C:16]1[N:17]=[C:18]([PH:32]([CH2:34][CH:39]([CH3:38])[CH3:58])=[O:33])[CH:19]=[C:20]([PH:22]([CH2:30][CH:49]([CH3:50])[CH3:48])=[O:23])[N:21]=1)=[O:15])[CH:6]([CH3:11])[CH3:7]

Participants

6

Reactant 5

HCID 12490074HCID 12490074, compoundHCID 12755210HCID 12755210, compoundHCID 20539491HCID 20539491, compoundHCID 20539499HCID 20539499, compoundHCID 54414513HCID 54414513, compound

Product 1

HCID 178454898HCID 178454898, compound

Procedure

If methyl ethylphenylphosphinite is used in place of methyl diphenylphosphinite in substantially the same aforesaid procedure of this example, 2,4,6-tris(ethylphenylphosphinyl)pyrimidine will be formed. If ethyl dipropylphosphinite is used, the product will be 2,4,6-tris(dipropylphosphinyl)pyrimidine. If methyl diisobutylphosphinite is used, 2,4,6-tris(isobutylphosphinyl)pyrimidine will be formed. If ethyl dibenzylphosphinite is used, the product will be 2,4,6-tris(dibenzylphosphinyl)pyrimidine.

Workup

  1. customwill be formed

Sources & evidence

ORD record
ord-db7a9a5978724ce4a9b79d5c097579ac
Source dataset
uspto-grants-1980_11
Patent number
US04234729

Reaction notes

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