Methyldichlorosilane → HCID 123155376, compound

Participants

Reaction Steps

As described in Example 2, 2.92 g (0.0221 mol) of dicyclopentadiene, 3.79 g (0.0331 mol) of methyldichlorosilane, 0.0602 g 1% Pd on Charcoal, 86 μL (0.000267 mol) of tributylphosphine and 4 mL of toluene and 2 mL of hexadecane were placed in a reactor. The reactor was sealed and the reaction was performed at 180° C. for 1 hour. Products were subject to simple vacuum distillation, thereby providing a mixture (12.8 g) of (2-cyclopentenyl)methyldichlorosilane (3.8 g, 63%), other unreacted reactants, toluene, hexadecane, and unidentified compounds. Besides, tetrakis(triphenylphosphine)palladium also showed catalyst effect.

Provenance & Evidence