Methyl chloroglyoxylate → HCID 11126698, compound

HRID 2250359Notes

Reaction equation

[CH:1]1([Mg]Br)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.Cl[C:10](=[O:15])[C:11]([O:13][CH3:14])=[O:12]>>[CH:1]1([C:10](=[O:15])[C:11]([O:13][CH3:14])=[O:12])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

Reactant 2

HCID 79846Methyl chloroglyoxylate

HCID 178419651HCID 178419651, compound

Product 1

HCID 11126698HCID 11126698, compoundYield 65%

Procedure

The title compound (1.1 g, 65%) as a colorless oil was prepared from cyclohexyl-magnesium bromide and methyl chlorooxoacetate by the procedures described in F. Babudri et al., Tetrahedron, 52 (42), pp. 13512-20 (1996).

Sources & evidence

ORD record: ord-c2a77e2652d54bc49716fae946616b92
Source dataset: uspto-grants-2008_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07317012B2

Reaction notes

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