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HRID2251768

反应详情

EQUATION

反应方程式

HRID 2251768 的结构方程式

REACTANTS

反应物

3
结构：O=S(=O)([O-])C(F)(F)F
HCID2758875

Trifluoromethanesulfonate

CF3O3S-

2 次

结构：C=C[C@@H](C)CC[C@@H]1C[C@H](O)C[C@](OC)([C@@H]2CSC(=O)N2Cc2ccc(OC)cc2)O1
HCID59644066

未命名化合物

结构：C=CCCC[C@@H]1C[C@H](O)C[C@](OC)([C@@H]2CSC(=O)N2Cc2ccc(OC)cc2)O1
HCID59644085

未命名化合物

PRODUCTS

生成物

1
结构：C=CCC/C(C)=C\C(=O)O[C@@H]1C[C@@H](CC[C@H](C)C=C)O[C@@](OC)([C@@H]2CSC(=O)N2Cc2ccc(OC)cc2)C1
HCID25215543

未命名化合物

PROCEDURE

实验过程

Triflate formation using the method shown in Example 22, with the modification that (R)-4-((2R,4S,6R)-4-hydroxy-2-methoxy-6-((S)-3-methylpent-4-enyl)-tetrahydro-2H-pyran-2-yl)-3-(4-methoxybenzyl)thiazolidin-2-one was substituted for (R)-4-((2R,4S,6R)-4-hydroxy-2-methoxy-6-(pent-4-enyl)-tetrahydro-2H-pyran-2-yl)-3-(4-methoxybenzyl)thiazolidin-2-one, followed by triflate displacement using the method shown in Example 23, afforded the title compound.