Pyridinium chloride → HCID 85087452, compound

HRID 2252364Notes

Reaction equation

HRID 2252364 reaction equation
[F:1][C:2]1[C:7]([F:8])=[C:6]([F:9])[C:5]([F:10])=[C:4]([F:11])[C:3]=1[CH:12]=[CH:13][C:14]1[CH:19]=[C:18]([O:20]C)[C:17]([CH:22]([CH3:24])[CH3:23])=[C:16]([O:25]C)[CH:15]=1.Cl.N1C=CC=CC=1>>[F:1][C:2]1[C:7]([F:8])=[C:6]([F:9])[C:5]([F:10])=[C:4]([F:11])[C:3]=1[CH:12]=[CH:13][C:14]1[CH:15]=[C:16]([OH:25])[C:17]([CH:22]([CH3:23])[CH3:24])=[C:18]([OH:20])[CH:19]=1

Participants

3

Reactant 2

HCID 10176127Pyridinium chlorideHCID 85960785HCID 85960785, compound

Product 1

HCID 85087452HCID 85087452, compoundYield 21%

Procedure

This material was prepared from 1-(2,3,4,5,6-pentafluorophenyl)-2-(3,5-dimethoxy-4-i-propylphenyl)ethene and pyridine hydrochloride in 21% yield in the same way as described in example 34. 1HNMR (CDCl3, ppm): δ 1.40 (d, J=7.2 Hz, 6H), 3.53 (d, J=7.2 Hz, 6H), 4.91 (s, 2H), 6.55 (s, 2H), 6.86 (d, J=17 Hz, 1H), 7.28 (d, J=17 Hz, 1H).

Sources & evidence

ORD record
ord-e192e802943f4dddbaadd22507e8f7c3
Source dataset
uspto-grants-2008_01
Patent number
US07321050B2

Reaction notes

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