HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylbenzenesulfonamide → N-{3-[4-(1,2-diphenyl-but-1-enyl)-phenyl]-acryloyl}-2-methyl-benzenesulfonamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylbenzenesulfonamide | HCID 6924 | — |
| Reactant | 3-[4-(Z)-(1,2-diphenylbut-1-enyl)phenyl]-acrylic acid | HCID 3036152 | — |
| Product | N-{3-[4-(1,2-diphenyl-but-1-enyl)-phenyl]-acryloyl}-2-methyl-benzenesulfonamide | HCID 69781000 | — |
Reaction Steps
Prepared by coupling 1a and o-toluenesulfonamide in accordance with Procedure 1, Method B described hereinabove. Yield (37%); 1H NMR (CD3OD) δ 11.63 (br s, 1H), 7.54 (d, J=15.7 Hz, 2H), 7.39-7.09 (m, 15H), 6.87 (d, J=8.0 Hz, 2H), 6.81 (s, 1H), 6.41 (d, J=15.7 Hz, 1H), 3.02-2.73 (s, 3H), 2.37 (q, J=7.3 Hz, 2H), 0.83 (t, J=7.3 Hz, 3H); APcI m/z: 508 (M+H+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07323587B2 |
| Source dataset | uspto-grants-2008_01 |
| ORD ID | ord-af34810cec7d45c4a38c9f30c10db2c7 |
| Source note | uspto-grants-2008_01 |