HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → Methyl 3-(chlorocarbonyl)-5-nitrobenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 1,3-Benzenedicarboxylic acid, 5-nitro-, 1-methyl ester | HCID 74776 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Methyl 3-(chlorocarbonyl)-5-nitrobenzoate | HCID 74774 | — |
Reaction Steps
Heat 3-methoxycarbonyl-5-nitrobenzoic acid (2.0 g=8.9 mmol) with SOCl2 (2.1 g=18 mmol) in toluene at reflux 1 hr. Concentrate to obtain 3-methoxycarbonyl-5-nitrobenzoyl chloride, m.p. 66°-8° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05232920 |
| Source dataset | uspto-grants-1993_08 |
| ORD ID | ord-58d1af3e19f64ebeaafb93c0ff9d8920 |
| Source note | uspto-grants-1993_08 |