Nitric Acid → HCID 67838413, compound

HRID 2253658Notes

Reaction equation

HRID 2253658 reaction equation
[O:1]([C:8]1[CH:9]=[N:10][CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+:14]([O-:17])([OH:16])=[O:15]>C(O)C>[N+:14]([O-:17])([OH:16])=[O:15].[O:1]([C:8]1[CH:9]=[N:10][CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 2005103-Phenoxypyridine

Product 1

HCID 67838413HCID 67838413, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A solution of 9 g. of 3-phenoxypyridine in 20 ml. of absolute ethanol is treated with 9 g. of 70% nitric acid with stirring. The resulting mixture is diluted with 200 ml. of ether and the crystalline precipitate of 3-phenoxypyridine nitrate is collected by filtration, washed with ether and dried at reduced pressure; m.p. 103.5°-105° C.

Workup

  1. additionThe resulting mixture is diluted with 200 ml
  2. filtrationof ether and the crystalline precipitate of 3-phenoxypyridine nitrate is collected by filtration
  3. washwashed with ether
  4. customdried at reduced pressure

Sources & evidence

ORD record
ord-34b1b4c1588d48528a996d26398a972c
Source dataset
uspto-grants-1993_08
Patent number
US05232934

Reaction notes

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