4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride

HRID 225401Notes

Reaction equation

HRID 225401 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>O>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 78104-ChlorotolueneHCID 15680p-Tolyl sulfoxide

Product 1

HCID 5351245Tris(4-methylphenyl)sulfanium Chloride

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The target compound was obtained by following the procedure of Synthesis Example 1 aside from using bis(4-methylphenyl)sulfoxide instead of the diphenyl sulfoxide and 4-chlorotoluene instead of the chlorobenzene in Synthesis Example 1, and increasing the amount of water for extraction.

Workup

  1. customThe target compound was obtained
  2. customthe procedure of Synthesis Example 1 aside
  3. customin Synthesis Example 1
  4. extractionfor extraction

Sources & evidence

ORD record
ord-7876b576d4b24804986972cc3496348e
Source dataset
uspto-grants-2009_07
Patent number
US07556909B2

Reaction notes

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