HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichlorodifluoromethane → 4-Bromo-2,2,4,5,5-pentafluoro-1,3-dioxolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichlorodifluoromethane | HCID 6391 | — |
| Reactant | 1-Bromo-1,2,2-trifluoroethene | HCID 11730 | — |
| Reactant | Bis(fluoroxy)perfluoromethane | HCID 140054 | — |
| Solvent | Nitrogen | HCID 947 | — |
| Product | 4-Bromo-2,2,4,5,5-pentafluoro-1,3-dioxolane | HCID 19745410 | — |
Reaction Conditions
| Temperature | -70 °C |
|---|
Reaction Steps
Into a multineck glass reactor equipped with: magnetic entrainment mechanical stirrer, reflux cooler, thermocouple, inner plunging pipes for introducing the reagents, and maintained at a temperature of -70° C., there were simultaneously fed--after having introduced 75 ml of dichlorodifluoromethane--0.75 l of bis(fluoroxy)difluoromethane at a flowrate of 0.375 l/h diluted with N2 (0.5 l/h) and bromotrifluoroethylene (5.4 g/h) for 2 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05235074 |
| Source dataset | uspto-grants-1993_08 |
| ORD ID | ord-2446786a72964a878d77a35fabb81709 |
| Source note | uspto-grants-1993_08 |