HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 86747097, compound → HCID 54453846, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 86747097 | HCID 86747097 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 54453846 | HCID 54453846 | — |
Reaction Steps
Alcohol 20 (obtained as described in Example 14) is oxidized with active manganese dioxide (5 g) in dichloromethane until the disappearance of starting material (monitored by thin layer chromatography on silica gel, dichloromethane solvent) affords the desired product, 7-(1-azulenyl)-2-fluoro-3-methyl- 2,4,6-heptatrienal, 21 , as a 2-cis/2-trans mixture as determined by NMR spectroscopy.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05235076 |
| Source dataset | uspto-grants-1993_08 |
| ORD ID | ord-6385b14c75b74cdbadd199a33edf46d6 |
| Source note | uspto-grants-1993_08 |