HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-[3-(Bromomethyl)phenyl]thiophene → HCID 54473318, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-[3-(Bromomethyl)phenyl]thiophene | HCID 13245926 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | HCID 178470113 | HCID 178470113 | — |
| Product | HCID 54473318 | HCID 54473318 | — |
Reaction Steps
The same reaction as in Referential Example 57 is carried out except using 3-(3-thienyl)benzyl bromide [prepared by reducing 3-(3-thienyl)benzaldehyde with sodium borohydride, followed by reacting with phosphorus tribromide] and 4-carboethoxy-2-mercaptothiazole [J. Org. Chem., 25, 1337 (1960)], and the resulting ester compound is reduced with lithium aluminium hydride to give the captioned compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05234946 |
| Source dataset | uspto-grants-1993_08 |
| ORD ID | ord-409a3a1ae6184924a181b6393fdff09d |
| Source note | uspto-grants-1993_08 |