HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → 3-Formyl-2-hydroxy-5-nitrobenzyltriphenylphosphonium chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 3-(Chloromethyl)-2-hydroxy-5-nitrobenzaldehyde | HCID 99380 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 3-Formyl-2-hydroxy-5-nitrobenzyltriphenylphosphonium chloride | HCID 86747116 | 86% |
Reaction Steps
A 4.53 g (20.9 mmoles) quantity of 3-chloromethyl-5-nitrosalicylaldehyde and 5.48 g (20.9 mmoles) of triphenylphosphine were dissolved in 30 ml of benzene and the solution obtained was refluxed with heating for 8 hours. After the reaction, the precipitate obtained was isolated by filtration, washed thoroughly with acetone and dried, giving 8.63 g (yield: 86%) of 3-formyl-2-hydroxy-5-nitrobenzyltriphenylphosphonium chloride as a yellow powder.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05236958 |
| Source dataset | uspto-grants-1993_08 |
| ORD ID | ord-b91ef159c6d44bfc8d4a616a5245177d |
| Source note | uspto-grants-1993_08 |