Benzoyl chloride → HCID 15617784, compound

HRID 2254923Notes

Reaction equation

HRID 2254923 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:13]=[CH:14][C:15]=1[Cl:16])[C:5]([NH:7][NH:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[O:6].[OH-].[Na+].[C:19](Cl)(=[O:26])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>C(Cl)Cl>[C:19]([N:8]([C:9]([CH3:12])([CH3:11])[CH3:10])[NH:7][C:5](=[O:6])[C:4]1[CH:13]=[CH:14][C:15]([Cl:16])=[C:2]([Cl:1])[CH:3]=1)(=[O:26])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1

Participants

5

Reactant 3

HCID 7412Benzoyl chlorideHCID 14798Sodium HydroxideHCID 3454435112226-05-8

Product 1

HCID 15617784HCID 15617784, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

3,4-Dichlorobenzoyl-2-tert-butylhydrazine (5.63 g, 0.0215 mole) is added to a rapidly stirring mixture of 40 mL of methylene chloride and 20 mL of 10% aqueous sodium hydroxide (2 g, 0.05 mole). Benzoyl chloride (d=1.211, 2.5 mL, 3.03 g, 0.0215 mole) in methylene chloride is added and the reaction mixture stirred vigorously for approximately three hours at ambient temperature. The resulting solid is collected and washed with water and methylene chloride.

Workup

  1. stirringthe reaction mixture stirred vigorously for approximately three hours at ambient temperature
  2. customThe resulting solid is collected
  3. washwashed with water and methylene chloride

Sources & evidence

ORD record
ord-96f9e4caa25f40e2bca269031448abfd
Source dataset
uspto-grants-1993_08
Patent number
US05237099

Reaction notes

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