Nitric Acid → HCID 178460811, compound

HRID 2255898Notes

Reaction equation

HRID 2255898 reaction equation
[CH2:1]([S:4][C:5]1[N:10]=[C:9]([OH:11])[CH:8]=[C:7]([OH:12])[N:6]=1)[CH2:2][CH3:3].[N+:13]([O-])([OH:15])=[O:14]>>[N+:13]([C:8]1[C:7]([OH:12])=[N:6][C:5]([S:4][CH2:1][CH2:2][CH3:3])=[N:10][C:9]=1[OH:11])([O-:15])=[O:14]

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 1784608102-(Propylthio)pyrimidine-4,6-diol

Product 1

HCID 178460811HCID 178460811, compound

Procedure

The product of step i) (2 g) was added to ice-cooled fuming nitric acid (10 ml) over 1 hour and stirred at 0° for a further 1 hour. Pouring into ice followed by drying afforded the sub-title compound as a beige solid (1.7 g).

Workup

  1. additionPouring into ice
  2. customby drying

Sources & evidence

ORD record
ord-f72718788b4d452e80865fddcb7877b8
Source dataset
uspto-grants-1997_08
Patent number
US05654285

Reaction notes

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