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HRID2256195

反应详情

EQUATION

反应方程式

HRID 2256195 的结构方程式

REACTANTS

反应物

2
结构：CSc1ncnc2nc[nH]c12
HCID5778

6-(methylsulfanyl)-7H-purine

C6H6N4S

结构：CC(=O)OC[C@H]1OC(Cl)[C@H](OC(C)=O)[C@@H]1OC(C)=O
HCID13384734

未命名化合物

PRODUCTS

生成物

2
结构：CSc1ncnc2c1ncn2[C@@H]1O[C@H](CO)[C@@H](O)[C@H]1O
HCID9570

6-Methylmercaptopurine ribonucleoside

C11H14N4O4S

结构：OC[C@H]1O[C@@H](n2cnc3c(S)ncnc32)[C@H](O)[C@@H]1O
HCID178521071

未命名化合物

PROCEDURE

实验过程

6-Methylmercaptopurine riboside is synthesized by condensing 6-methylmercaptopurine with 2,3,5-tri-O-acetyl-D-ribo-furanosyl chloride using the catalyst mercuric chloride followed by deacetylation. Alternatively, 6-methylmercaptopurine riboside can be produced directly by methylation of 6-thioinosine (Fox, J. J. et al., J. Am. Chem. Soc. 80: 1669, 1958).