HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethylaluminum chloride → 1-Octene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethylaluminum chloride | HCID 7277 | — |
| Reactant | Heptane | HCID 8900 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Product | 1-Octene | HCID 8125 | — |
| Product | 1,7-Octadiene | HCID 19460 | — |
Reaction Steps
A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 52 percent, inherent viscosity was 1.9 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05428209 |
| Source dataset | uspto-grants-1995_06 |
| ORD ID | ord-87da2cd7a1004668b0b227c1ea33b62b |
| Source note | uspto-grants-1995_06 |