Allyl chloride → HCID 178460918, compound

HRID 2258164Notes

Reaction equation

[CH2:1](Cl)[CH:2]=[CH2:3].Cl[SiH:6]1[CH2:11][CH2:10][CH:9]([C:12]2[CH:17]=[CH:16][C:15]([C:18]3[CH:23]=[CH:22][C:21]([CH2:24][CH2:25][CH3:26])=[CH:20][CH:19]=3)=[CH:14][CH:13]=2)[CH2:8][CH2:7]1>>[CH:3]([Si@H:6]1[CH2:11][CH2:10][C@H:9]([C:12]2[CH:17]=[CH:16][C:15]([C:18]3[CH:19]=[CH:20][C:21]([CH2:24][CH2:25][CH3:26])=[CH:22][CH:23]=3)=[CH:14][CH:13]=2)[CH2:8][CH2:7]1)=[CH:2][CH3:1]

Participants

Reactant 2

HCID 7850Allyl chloride

HCID 123686008HCID 123686008, compound

Product 1

HCID 178460918HCID 178460918, compound

Procedure

Preparation was conducted in the same manner as in Example 1 except for the fact that allyl chloride was used instead of n-propylbromide and that 4'-(4-chloro-4-silacyclohexyl)-4-n-propylbiphenyl was used instead of 4'-(4-chloro-4-silacyclohexyl)-4-fluorobiphenyl.

Workup

customPreparation

Sources & evidence

ORD record: ord-88bf216ddd1e41d594aa9028f5dc0253
Source dataset: uspto-grants-1997_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05659059

Reaction notes

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