1-Bromo-2-methylpropane → HCID 178455403, compound

HRID 2258165Notes

Reaction equation

HRID 2258165 reaction equation
[CH2:1](Br)[CH:2]([CH3:4])[CH3:3].Cl[SiH:7]1[CH2:12][CH2:11][CH:10]([C:13]2[CH:18]=[CH:17][C:16]([C:19]3[CH:24]=[CH:23][C:22]([O:25][CH:26]([F:28])[F:27])=[CH:21][CH:20]=3)=[CH:15][CH:14]=2)[CH2:9][CH2:8]1>>[CH2:1]([Si@H:7]1[CH2:8][CH2:9][C@H:10]([C:13]2[CH:14]=[CH:15][C:16]([C:19]3[CH:24]=[CH:23][C:22]([O:25][CH:26]([F:27])[F:28])=[CH:21][CH:20]=3)=[CH:17][CH:18]=2)[CH2:11][CH2:12]1)[CH:2]([CH3:4])[CH3:3]

Participants

3

Reactant 2

HCID 65551-Bromo-2-methylpropaneHCID 123521514HCID 123521514, compound

Product 1

HCID 178455403HCID 178455403, compound

Procedure

Preparation was conducted in the same manner as in Example 1 except for the fact that isobutyl bromide was used instead of n-propylbromide and that 4'-(4-chloro-4-silacyclohexyl)-4-difluoromethoxybiphenyl was used instead of 4'-(4-chloro-4-silacyclohexyl)-4-fluorobiphenyl.

Workup

  1. customPreparation

Sources & evidence

ORD record
ord-c6d4f6ea232e4dcfb2247c80deb9016c
Source dataset
uspto-grants-1997_08
Patent number
US05659059

Reaction notes

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