Pentaerythritol → HCID 21225080, compound

HRID 2258549Notes

Reaction equation

HRID 2258549 reaction equation
[OH:1][CH2:2][C:3]([CH2:8][OH:9])([CH2:6][OH:7])[CH2:4][OH:5].[C:10](Cl)(=[O:14])[CH2:11][CH2:12][CH3:13]>N1C=CC=CC=1>[C:10]([O:1][CH2:2][C:3]([CH2:8][OH:9])([CH2:6][OH:7])[CH2:4][OH:5])(=[O:14])[CH2:11][CH2:12][CH3:13]

Participants

4

Reactant 2

HCID 8285PentaerythritolHCID 8855Butyryl chloride

Product 1

HCID 21225080HCID 21225080, compoundYield 47%

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

In this example, the stoichiometry of Example 1 was modified using pentaerythritol (1.92 g; 14 mmol) and butyryl chloride (0.75 mL; 0.5 equiv) and pyridine (100 mL) to produce pentaerythritol monobutyrate (0.74 g; 47%).

Sources & evidence

ORD record
ord-14fe6f254bdf42f8b7ef179694de286d
Source dataset
uspto-grants-1997_08
Patent number
US05661181

Reaction notes

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