Ethyl Thioglycolate → HCID 54184237, compound

HRID 2259743Notes

Reaction equation

HRID 2259743 reaction equation
[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH2:2][SH:3].[CH:8]([C:10]1[CH:18]=[CH:17][C:13]2[O:14][CH2:15][O:16][C:12]=2[CH:11]=1)=[CH2:9]>>[O:14]1[C:13]2[CH:17]=[CH:18][C:10]([CH2:8][CH2:9][S:3][CH2:2][C:1]([O:5][CH2:6][CH3:7])=[O:4])=[CH:11][C:12]=2[O:16][CH2:15]1

Participants

3

Reactant 2

HCID 12185Ethyl ThioglycolateHCID 1389861,3-Benzodioxole, 5-ethenyl-

Product 1

HCID 54184237HCID 54184237, compoundYield 69.1%

Procedure

3.24 g of ethyl thioglycolate was added to 6 g of 5-ethenyl-1,3-benzodioxole and the mixture was stirred at room temperature for 14 h. The reaction product was purified according to silica gel column chromatography (benzene:ethyl acetate=40:1) to obtain 5 g of the intended compound in the form of a colorless oil.

Workup

  1. customThe reaction product was purified

Sources & evidence

ORD record
ord-73a1b60862c843dc9f694db20d9edb06
Source dataset
uspto-grants-1995_12
Patent number
US05475024

Reaction notes

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