HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiourea → HCID 68428752, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiourea | HCID 2723790 | — |
| Reactant | Methyl 2-(bromomethyl)benzoate | HCID 2734813 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 68428752 | HCID 68428752 | 105,697.797% |
Reaction Steps
A mixture of the crude bromide from Step 1 (7.2 g, 0.031 mmol) and thiourea (2.6 g, 35 mmol) in MeOH (40 mL) was heated to reflux for 4 h, cooled to room temperature, and concentrated to afford methyl 2-({[amino(imino)methyl]thio}methyl)benzoate hydrobromide (10 g, ca. 100%), which was used without purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07557135B2 |
| Source dataset | uspto-grants-2009_07 |
| ORD ID | ord-b44dfef5a5ee4568b7331c94f729811b |
| Source note | uspto-grants-2009_07 |