Prop-2-en-1-yl 3-nitrobenzoate → Allyl 3-aminobenzoate

HRID 2260770Notes

Reaction equation

HRID 2260770 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:13]=[CH:14][CH:15]=1)[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8])([O-])=O>CO>[NH2:1][C:4]1[CH:5]=[C:6]([CH:13]=[CH:14][CH:15]=1)[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8]

Participants

3

Reactant 1

HCID 14980143Prop-2-en-1-yl 3-nitrobenzoate

Product 1

HCID 18930599Allyl 3-aminobenzoate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Reduction of the above nitro compound by the method of Example 2, except that the solvent was methanol, gave allyl 3-aminobenzoate. Nmr (CDCl3): δ3.38 (br, 2H); 4.79 (dt, 2H); 5.24-5.44 (m, 2H); 5.93-6.09 (m, 1H); 6.86 (dm, 1H); 7.21 (t, 1H); 7.37 (t, 1H); 7.45 (dt, 1H).

Sources & evidence

ORD record
ord-5661aa7e63b747d7bb19892e37712fc5
Source dataset
uspto-grants-1995_12
Patent number
US05478820

Reaction notes

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