Nitric Acid → HCID 19432542, compound

HRID 2264138Notes

Reaction equation

HRID 2264138 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[CH:9][C:10]=1[OH:11])[C:5]([OH:7])=[O:6].[N+:12]([O-])([OH:14])=[O:13]>>[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[C:9]([N+:12]([O-:14])=[O:13])[C:10]=1[OH:11])[C:5]([OH:7])=[O:6]

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 198603-Chloro-4-hydroxybenzoic acid

Product 1

HCID 19432542HCID 19432542, compound

Conditions

Temperature
20 °C

Procedure

3-chloro-4-hydroxybenzoic acid (5.0 g) was added in small portions to stirred fuming HNO3 (90%, 15 mL) cooled on ice. After completion of addition, the orange mixture was allowed to warm to 20° C. and stirring was continued for 2 h. Ice water (50 mL) was added, and the precipitated product was collected by vacuum filtration to yield 5.4 g of 3-chloro-4-hydroxy-5-nitrobenzoic acid as a bright yellow solid.

Workup

  1. temperaturecooled on ice
  2. additionAfter completion of addition
  3. filtrationthe precipitated product was collected by vacuum filtration

Sources & evidence

ORD record
ord-dd964c5f19a94733a51026a4054eccd5
Source dataset
uspto-grants-2010_12
Patent number
US07855192B2

Reaction notes

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