4-Fluorobenzoyl chloride → HCID 178505540, compound

HRID 2264207Notes

Reaction equation

HRID 2264207 reaction equation
[F:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=O)=[CH:4][CH:3]=1.[Cl:11][C:12]1[CH:13]=[N:14][CH:15]=[CH:16][C:17]=1[C:18]1[C:23]([C:24]2[CH:29]=[CH:28][N:27]=[CH:26][C:25]=2[F:30])=[CH:22][C:21]([NH2:31])=[C:20]([NH2:32])[N:19]=1>>[Cl:11][C:12]1[CH:13]=[N:14][CH:15]=[CH:16][C:17]=1[C:18]1[N:19]=[C:20]2[NH:32][C:6]([C:5]3[CH:9]=[CH:10][C:2]([F:1])=[CH:3][CH:4]=3)=[N:31][C:21]2=[CH:22][C:23]=1[C:24]1[CH:29]=[CH:28][N:27]=[CH:26][C:25]=1[F:30]

Participants

3

Reactant 2

HCID 678794-Fluorobenzoyl chlorideHCID 59595993HCID 59595993, compound2×

Product 1

HCID 178505540HCID 178505540, compound

Procedure

Following the same protocol as in Example 2, but using 4-fluorobenzoylchloride and 3-chloro-3″-fluoro-4,2′:3′,4″-terpyridine-5′,6′-diamine (Intermediate 8), the title compound was obtained as a white solid (13 mg, 12%).

Sources & evidence

ORD record
ord-a50d7101e1e94ef193022b485fb1d32c
Source dataset
uspto-grants-2010_12
Patent number
US07855202B2

Reaction notes

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