HCID 57837883, compound → HCID 23112245, compound

HRID 2264331Notes

Reaction equation

HRID 2264331 reaction equation
C([O:3][C:4](=O)/[C:5](/[CH3:20])=[CH:6]/[C:7]1[CH:16]=[CH:15][C:10]([C:11]([O:13][CH3:14])=[O:12])=[CH:9][C:8]=1[N+:17]([O-])=O)C>[Pd].C(O)C>[CH3:20][CH:5]1[CH2:6][C:7]2[C:8](=[CH:9][C:10]([C:11]([O:13][CH3:14])=[O:12])=[CH:15][CH:16]=2)[NH:17][C:4]1=[O:3]

Participants

4

Reactant 1

HCID 57837883HCID 57837883, compound

Product 1

HCID 23112245HCID 23112245, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

Methyl 4-[(1E)-3-ethoxy-2-methyl-3-oxoprop-1-en-1-yl]-3-nitrobenzoate and palladium/carbon were added to ethanol and the whole was stirred under a hydrogen atmosphere to obtain methyl 3-methyl-2-oxo-1,2,3,4-tetrahydroquinolin-7-carboxylate.

Sources & evidence

ORD record
ord-06b4870d224b44be8f6fc280fbb63e38
Source dataset
uspto-grants-2010_12
Patent number
US07855198B2

Reaction notes

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