(4-Methoxyphenyl)hydrazine → HCID 178492064, compound

HRID 2265851Notes

Reaction equation

HRID 2265851 reaction equation
[F:1][C:2]1[CH:11]=[CH:10][C:9]2[NH:8][CH:7]=[C:6]3[C:12](=[O:21])[N:13]([C:15]4[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=4)[N:14]=[C:5]3[C:4]=2[N:3]=1.[CH3:22][O:23]C1C=CC(NN)=CC=1>>[F:1][C:2]1[CH:11]=[CH:10][C:9]2[NH:8][CH:7]=[C:6]3[C:12](=[O:21])[N:13]([C:15]4[CH:20]=[CH:19][C:18]([O:23][CH3:22])=[CH:17][CH:16]=4)[N:14]=[C:5]3[C:4]=2[N:3]=1

Participants

3

Reactant 2

HCID 77023(4-Methoxyphenyl)hydrazineHCID 178515199HCID 178515199, compound

Product 1

HCID 178492064HCID 178492064, compound

Procedure

The title compound was prepared following the procedure described in Step 3 for synthesis for 5a using 4-methoxyphenylhydrazine instead of phenylhydrazine. 1H-NMR (DMSO-d6) δ (ppm): 7.25 (1H, ddd, J=7.14, 4.67, 1.10 Hz), 7.50 (1H, dd, J=8.79, 3.03 Hz),): 7.90 (1H, ddd, J=9.34, 7.42, 1.93 Hz), 8.14 (1H, brd, J=8.24 Hz), 8.28 (1H, ddd, J=9.06, 7.42, 7.14 Hz), 8.50 (1H, m), 8.84 (1H, s). m/z 282.3 (MH+).

Sources & evidence

ORD record
ord-110e3753fbf74956911ef1dabfdd2787
Source dataset
uspto-grants-2010_12
Patent number
US07858614B2

Reaction notes

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