HCID 86614951, compound → Carbon Dioxide

HRID 2266947Notes

Reaction equation

HRID 2266947 reaction equation
[H][H].[O:3]=[C:4]([O-:14])[C:5]([CH2:7][C@@H:8]([C@@H:10]([CH2:12][OH:13])[OH:11])[OH:9])=[O:6].[K+:15]>>[C:4](=[O:14])=[O:3].[O:3]=[C:4]([O-:14])[C:5]([CH2:7][C@@H:8]([C@@H:10]([CH2:12][OH:13])[OH:11])[OH:9])=[O:6].[K+:15]

Participants

4

Reactant 2

HCID 86614951HCID 86614951, compound2×HCID 178418361HCID 178418361, compound

Product 2

HCID 280Carbon DioxideHCID 86614951HCID 86614951, compound

Procedure

0.5 ml of a 31% hydrogen peroxyde solution were added to 5 ml of a 1M potassium 2-dehydro-3-deoxy-D-gluconate (KDG) solution at 25° C. The progression of KDG decarboxylation was followed both by the observation of bubbles resulting from the release of carbon dioxide and by the disappearance of KDG using the thin layer chromatography protocol described in example 2. Typically, after a 3 h period of reaction the concentration of residual KDG was less than 10 mM.

Sources & evidence

ORD record
ord-d57d308491374d2eb1b15d3a567688d7
Source dataset
uspto-grants-2010_12
Patent number
US07858775B2

Reaction notes

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