Tributyl(prop-1-yn-1-yl)stannane → HCID 68429629, compound

HRID 2267135Notes

Reaction equation

HRID 2267135 reaction equation
[N:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[F:10])=[N+:2]=[N-:3].[CH3:11][O:12][CH2:13][C:14]#[C:15][Si:16]([CH3:19])([CH3:18])[CH3:17].C([Sn](CCCC)(CCCC)C#CC)CCC>>[F:10][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[N:1]1[C:14]([CH2:13][O:12][CH3:11])=[C:15]([Si:16]([CH3:19])([CH3:18])[CH3:17])[N:3]=[N:2]1

Participants

4

Reactant 3

HCID 2733165Tributyl(prop-1-yn-1-yl)stannaneHCID 1003472943019-55-2HCID 116079241-Azido-2-fluorobenzene

Product 1

HCID 68429629HCID 68429629, compound

Procedure

A reaction was carried out by the method mentioned in Example 8-2 except that 1-azido-2-fluorobenzene was used in place of 1-azido-2-chlorobenzene used in Example 1-2 and that (3-methoxy-1-propynyl)-trimethylsilane prepared in the above 1) was used in place of tributyl (1-propynyl)tin used in Example 8-2 to give the title compound.

Sources & evidence

ORD record
ord-a37ec84c7257464d85a5f6418b5297a5
Source dataset
uspto-grants-2010_12
Patent number
US07858800B2

Reaction notes

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