Allyl 4-Hydroxybenzoate → HCID 18349877, compound

HRID 2268222Notes

Reaction equation

HRID 2268222 reaction equation
O[C:2]1[CH:13]=[CH:12][C:5]([C:6]([O:8][CH2:9][CH:10]=[CH2:11])=[O:7])=[CH:4][CH:3]=1.CC1(C)CCC(C)(C)C2C=C(C=CC(Cl)=O)C=CC1=2.[CH3:33][C:34]1([CH3:60])[CH2:43][CH2:42][C:41]([CH3:45])([CH3:44])[C:40]2[CH:39]=[C:38]([CH:46]=[CH:47][C:48]([O:50]C3C=CC=CC=3C([O-])=O)=[O:49])[CH:37]=[CH:36][C:35]1=2>>[CH3:33][C:34]1([CH3:60])[CH2:43][CH2:42][C:41]([CH3:44])([CH3:45])[C:40]2[CH:39]=[C:38](/[CH:46]=[CH:47]/[C:48]([O:50][C:12]3[CH:13]=[CH:2][CH:3]=[CH:4][C:5]=3[C:6]([O:8][CH2:9][CH:10]=[CH2:11])=[O:7])=[O:49])[CH:37]=[CH:36][C:35]1=2

Participants

4

Reactant 3

HCID 11171300Allyl 4-HydroxybenzoateHCID 73431552HCID 73431552, compoundHCID 734315563-(5,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)acryloyl chloride

Product 1

HCID 18349877HCID 18349877, compound

Procedure

In a similar manner to that of Example 11(b), by reaction of 710 mg (4 mmol) of allyl 4-hydroxybenzoate with 1 g (3.62 mmol) of 3-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)acryloyl chloride obtained in Example 1(c), 500 mg (33%) of allyl E)-2-[3-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-2-naphthyl)acryloyloxy]benzoate, with a melting point of 92-3° C., are obtained.

Workup

  1. customwith a melting point of 92-3° C., are obtained

Sources & evidence

ORD record
ord-31106fd082864c00985b7770e1b71576
Source dataset
uspto-grants-2001_12
Patent number
US06326510B1

Reaction notes

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