Borane → HCID 12144236, compound

HRID 2268720Notes

Reaction equation

HRID 2268720 reaction equation
Cl[B:2]([C:14]1[C:19]([F:20])=[C:18]([F:21])[C:17]([F:22])=[C:16]([F:23])[C:15]=1[F:24])[C:3]1[C:8]([F:9])=[C:7]([F:10])[C:6]([F:11])=[C:5]([F:12])[C:4]=1[F:13].Cl[SiH](C)C.B>>[F:20][C:19]1[C:14]([BH:2][C:3]2[C:4]([F:13])=[C:5]([F:12])[C:6]([F:11])=[C:7]([F:10])[C:8]=2[F:9])=[C:15]([F:24])[C:16]([F:23])=[C:17]([F:22])[C:18]=1[F:21]

Participants

4

Reactant 3

HCID 6331BoraneHCID 66108ChlorodimethylsilaneHCID 10959856CHLOROBIS(PENTAFLUOROPHENYL)BORANE

Product 1

HCID 12144236HCID 12144236, compound

Procedure

6.9 g (20 mmol) of chlorobis(pentafluorophenyl)borane are cooled to −78° C., and 8.9 g (100 mmol) of chlorodimethylsilane are slowly added dropwise. On warming to room temperature, the borane dissolves and a white precipitate is formed. The mixture is subsequently stirred for 1 hour and the precipitate is filtered off and washed with 20 ml of pentane.

Workup

  1. customa white precipitate is formed
  2. filtrationthe precipitate is filtered off
  3. washwashed with 20 ml of pentane

Sources & evidence

ORD record
ord-b2c9f9d38c6a488f965ec12040537886
Source dataset
uspto-grants-2001_12
Patent number
US06329313B1

Reaction notes

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