Diisobutylaluminumhydride → HCID 22493621, compound

HRID 2269238Notes

Reaction equation

HRID 2269238 reaction equation
[CH:1]([N:4]1[C:12]2[CH:11]=[CH:10][CH:9]=[C:8]([C:13](OC(C)C)=[O:14])[C:7]=2[CH:6]=[CH:5]1)([CH3:3])[CH3:2].[H-].C([Al+]CC(C)C)C(C)C>[O-2].[O-2].[Mn+4]>[CH:1]([N:4]1[C:12]2[CH:11]=[CH:10][CH:9]=[C:8]([CH:13]=[O:14])[C:7]=2[CH:6]=[CH:5]1)([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 21225700DiisobutylaluminumhydrideHCID 22493569HCID 22493569, compound

Product 1

HCID 22493621HCID 22493621, compound

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

Isopropyl 1-isopropylindole-4-carboxylate (2.6 g) was reduced by diisobutyl aluminum hydride, followed by oxidation with manganese dioxide, whereby the title compound was obtained.

Sources & evidence

ORD record
ord-601f934afa2740d5ac80c0267a85a1c8
Source dataset
uspto-grants-2001_12
Patent number
US06329402B1

Reaction notes

Loading…