Stannous Chloride → HCID 88201970, compound

HRID 2269427Notes

Reaction equation

HRID 2269427 reaction equation
[CH2:1]([O:8][N:9]=[C:10]([C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([N+:25]([O-])=O)[CH:20]=1)[C:11]1[CH:16]=[CH:15][C:14]([O:17][CH3:18])=[CH:13][CH:12]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Sn](Cl)Cl>>[CH2:1]([O:8][N:9]=[C:10]([C:11]1[CH:12]=[CH:13][C:14]([O:17][CH3:18])=[CH:15][CH:16]=1)[C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([NH2:25])[CH:20]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 88201839HCID 88201839, compound

Product 1

HCID 88201970HCID 88201970, compound

Procedure

In a similar manner to that described in Example (1b), the mixture (752 mg) of isomer A and B of 4-methoxyphenyl 3-nitrophenyl ketone O-benzyloxime and tin (II) chloride (1.97 g) were reacted, to afford a mixture of isomer A/isomer B=½ of the title compound as a yellow oil.

Workup

  1. customto afford

Sources & evidence

ORD record
ord-36a35169dd0c420ca69ab0c74727e95b
Source dataset
uspto-grants-2001_12
Patent number
US06329405B1

Reaction notes

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