Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | Cyclohexane, (ethenyloxy)- | HCID 75129 | — |
| Product | 3-Cyclohexyloxyacryloyl chloride | HCID 53968361 | 88% |
Reaction Steps
50 g (0.5 mol) of phosgene are condensed into a stirred apparatus fitted with −78° C.-cooling. Over a period of 3 hours, 50.5 g (0.4 mol) of cyclohexyl vinyl ether are subsequently added dropwise at 20° C. The mixture is then stirred at 50° C. for 5 hours. The excess phosgene is flushed out with nitrogen, and the crude product is worked up by distillation. At 110° C./2.5 mbar, 66.4 g (88%) of the product of value were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06329530B1 |
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| Source dataset | uspto-grants-2001_12 |
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| ORD ID | ord-f58f485e8e744b49b0af14d838d71d6c |
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| Source note | uspto-grants-2001_12 |
|---|
